Catalysis – Page 10
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Research
Hydrogen bonds are single atom nickel’s secret for carbon dioxide reduction
Computational calculations show that hydrogen atoms and charge capacity are behind nickel’s high activity and selectivity in electrochemical carbon dioxide reduction
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Research
Counterintuitive catalyst gives purer products when used in less enantiopure form
Unusual example of ‘hyperpositive’ nonlinear effect is a first for asymmetric catalysis
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Research
Rotaxane–gold complex is in good shape for catalysis
A new type of catalyst containing a mechanically planar chiral rotaxane shows promise for organic synthesis
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Research
Platinum makes PVC production greener and cheaper
A new single-atom catalyst could replace toxic mercury in the manufacture of vinyl chloride
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Research
Light-harvesting clusters and titanium dioxide cooperate to fix nitrogen
Atomically precise metal clusters continue to gather momentum by catalysing the production of ammonia
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Business
Solar-powered water purification
Majico’s photocatalytic water kiosks are increasing access to affordable drinking water in Tanzania
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Research
Durable catalyst could enable large scale conversion of carbon dioxide to syngas
Nanocatalysts on crystalline supports show remarkable stability producing hydrogen and carbon monoxide
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Research
Catalyst rapidly turns carbon dioxide into simple chemicals breaking activity record
Ionomer coating improves gas transport to electrode surface
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Research
Nickel catalyst switches on double stereochemistry in reaction between racemic alkanes
First-of-its-kind reaction creates stereocentres by stitching together racemic nucleophiles and electrophiles
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Research
Cobalt makes a comeback in hydroformylation catalysis
Cationic cobalt catalyst could drive down costs in widely-used process
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Opinion
Exploring nickel reactivity in C–H activation chemistry
Coming closer to an alternative for palladium
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Research
Grinding out single-atom catalysts made simple by ball mill
No compromise on quality of heterogeneous catalysts made on kilogram scale
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Research
Catalyst breaks sulfur–sulfur bonds to give new life to tired tyres
Process recovers organic components that can become new elastomers
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Research
‘Ideal’ water splitting catalysts actually exist, simulations find
New computational model could accelerate the discovery of cheaper and more efficient catalysts
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Research
Flow synthesis produces chiral intermediate for antidepressant drug
The first solvent-free organocatalytic flow process yields the key chiral intermediate for paroxetine on a multigram-scale
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Research
Chemists taken aback as dinitrogen found to speed up some reactions
Warnings that nitrogen should no longer be considered just an inert carrier gas
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Research
Light intensity changes can switch photocatalyst between one- and two-photon mechanisms
Simple optical lens behind strategy for manipulating photochemical reactivity
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Article
Johnson Matthey enzyme technology for a clean and healthy tomorrow
Enzymes have evolved into nature’s reaction facilitators over millions of years and their unique catalytic abilities drive science by connecting essential life elements
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Feature
Single-atom catalysis
Single atom and hierarchical nanopore catalysts are reducing the need for precious metals, and could clean up the energy and chemical industries, finds Andy Extance